Brad Pitt has 'apologized' to Jennifer Aniston for past relationship issues: report

The former duo made their red carpet debut in September 1999 at the Emmys before getting engaged two months later. They tied the knot in July 2000 in a Malibu, Calif. ceremony and were joined by several of their A-list pals, including Cameron Diaz, Salma Hayek and Aniston's "Friends" co-stars. They divorced in 2005.